Chemistry Lesson: The Hottest Onscreen Couples

From Rob Pattinson & Reese Witherspoon in Water for Elephants to Brad & Angelina, see the big screen's most sizzling duos (20 Photos)

Nisha Gopalan on Apr 22, 2011 at 3:56AM

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Chemistry Lesson: The Hottest Onscreen Couples

Twentieth Century Fox

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Brad Pitt and Angelia Jolie
'Mr. & Mrs. Smith'

Mr. & Mrs. Smith took that old adage "Take my wife, please!" and jettisoned it to an extreme. Angelina Jolie and Brad Pitt, as top-tier assassins, channeled marital tension into an explosive physicality that culminated in glass-shattering passion that should've come with a "don't try this at home" warning. Their chemistry in the 2005 film was undeniable, and at the time, being knee-deep in a "were they or weren't they" discussion amid Pitt's divorce from Jennifer Aniston, only added to the voyeuristic intrigue.

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