When Brad Pitt and Jennifer Aniston announced plans to divorce in March 2005, it was as if Barbie and Ken's Dream House had coming crashing down before our eyes. No one could believe that America’s golden couple had decided to part ways -- but what was even more shocking was how quickly Brad moved on. Rumors circulated during their separation that Pitt had been seeing his Mr. and Mrs. Smith costar, Angelina Jolie, while he was with Jen -- and Angie later admitted that she fell in love with him on the set of their 2005 film. (Though Pitt insists he did not cheat.) But it wasn’t until January 2006 (three months after the divorce was finalized), that they finally admitted that not only were they a couple, but they were also expecting their first child together. Six years later, the parents of six are now set to wed!