Secret Mission: John Smith (Brad Pitt) lives a double life -- top-secret assassin by day, mundane married man by night. When he discovers his seemingly ordinary wife, Jane (Angelina Jolie), is actually a rival spy, he must find a way to eliminate the competition and save his marriage.
Why We Love Him: Even as mild-mannered John, Pitt has an irresistible spark of mischief in his eyes, melting even Jolie’s famous ice-queen gaze. Of course, the true fun is watching real-life sparks ignite between Pitt (still wed to Jennifer Aniston during filming) and his leading lady. The lines he purrs in their now-famous tango scene make us blush.