Reese Witherspoon didn't necessarily find her Prince Charming away from the bright lights of Hollywood, but her hot new hubby Jim Toth is a behind-the-scenes kind of guy. A CAA talent agent, Toth and the This Means War star met at a party when one of Toth's drunk buddies hit on Reese. "Jim came over and said, 'Please excuse my friend, he's just broken up with someone,'" Witherspoon, 35, recalls to Elle magazine. "I remember thinking ... Jim was a really good friend, pulling (his drunk pal) out of that situation. That's just kind of who he is, a really good person." Reese, who has had high-profile relationships with ex-husband Ryan Philippe and ex-boyfriend Jake Gyllenhaal, ended up falling for the tall, handsome, down-to-earth guy and they married on March 26. "I've never had anybody like (him) in my life," gushed Witherspoon to Elle. "Jim's like, 'I'm gonna show you every day what a good partner is, what a good person is. I'm going to take care of you. I'm going to do it so much that you're gonna get used to it.'" Swoon!