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Spray the insert of a large slow cooker with nonstick cooking spray.
In a small bowl, stir together the mustard, shallots, thyme, cayenne, and ½ teaspoon salt. Brush the chicken pieces with the mixture, turning to coat all sides. Place the chicken in the cooker.
Cover and cook on low for 4 to 6 hours, or until the chicken is very tender and coming away from the bone.
Meanwhile, melt the butter in a large skillet. Add the bread crumbs and a pinch of salt. Cook over medium heat, stirring occasionally, for 5 minutes, or until the crumbs are lightly toasted.
Place the chicken pieces on a platter. Sprinkle with the crumb mixture, patting it on so that it adheres. Serve hot or cold.