Mismatched Celebrity Couples 0 Chimes

ADVERTISEMENT: Sometimes love can happen with the least expected person. Just like these improbable celebrity pairs, a mismatched couple discovers that they are actually made for each other in 'The Ugly Truth.' Get it on Sony Pictures Blu-ray and DVD on November 10.

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Demi Moore & Ashton Kutcher

After two failed marriages, a 15-year age difference didn’t stop big-screen star Demi Moore, 46, from finding new love with sitcom hunk Ashton Kutcher, 31, in 2003. Ignoring skeptics and tons of late-night TV “cougar” jokes, the couple married in September 2005 and Ashton became a loving stepdad to Demi’s daughters, Rumor, 21, Scout, 18, and Tallulah, 15. Ashton, who frequently goes on Twitter to gush about his gorgeous wife, confessed to Oprah Winfrey: “I love being with her. She makes me a better person.”