Most beautiful couple of the year? Sure looks like it! Ryan Reynolds and Blake Lively, who were first spotted together a year ago after starring in The Green Lantern, tied the knot on Sept. 9, at a plantation just outside Charleston, S.C. A source confirmed to People that the Gossip Girl star and the Safe House actor exchanged vows in a white tent ceremony. Lively's close friend Florence Welch (of Florence and the Machine) performed three songs during the festivities. This was the second trip down the aisle for Reynolds, who was previously married to actress Scarlett Johansson.